Cargando…
Highly Active Cooperative Lewis Acid—Ammonium Salt Catalyst for the Enantioselective Hydroboration of Ketones
Enantiopure secondary alcohols are fundamental high‐value synthetic building blocks. One of the most attractive ways to get access to this compound class is the catalytic hydroboration. We describe a new concept for this reaction type that allowed for exceptional catalytic turnover numbers (up to 15...
Autores principales: | Titze, Marvin, Heitkämper, Juliane, Junge, Thorsten, Kästner, Johannes, Peters, René |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986937/ https://www.ncbi.nlm.nih.gov/pubmed/33210781 http://dx.doi.org/10.1002/anie.202012796 |
Ejemplares similares
-
Silyl Anion Initiated Hydroboration of Aldehydes and Ketones
por: Stanford, Martin W., et al.
Publicado: (2020) -
Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
por: Zhang, Guoqi, et al.
Publicado: (2022) -
Photocontrolled Cobalt Catalysis for Selective Hydroboration of α,β‐Unsaturated Ketones
por: Beltran, Frédéric, et al.
Publicado: (2020) -
Enantioselective
Rhodium(III)-Catalyzed Markovnikov
Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017) -
s-Block Metal Catalysts for the Hydroboration
of Unsaturated Bonds
por: Magre, Marc, et al.
Publicado: (2022)