Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence

[Image: see text] Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}(7)–corrole(•2–) character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {...

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Detalles Bibliográficos
Autores principales: Rahman, Md. Hafizur, Ryan, Michael D., Vazquez-Lima, Hugo, Alemayehu, Abraham, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997370/
https://www.ncbi.nlm.nih.gov/pubmed/32053351
http://dx.doi.org/10.1021/acs.inorgchem.9b03613

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997370/
https://www.ncbi.nlm.nih.gov/pubmed/32053351
http://dx.doi.org/10.1021/acs.inorgchem.9b03613

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