Cargando…
Infrared Spectroelectrochemistry of Iron-Nitrosyl Triarylcorroles. Implications for Ligand Noninnocence
[Image: see text] Recent DFT calculations have suggested that iron nitrosyl triarylcorrole complexes have substantial {FeNO}(7)–corrole(•2–) character. With this formulation, reduction of Fe(C)(NO) complexes, where C = triarylcorrole, should be centered on the corrole macrocycle rather than on the {...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997370/ https://www.ncbi.nlm.nih.gov/pubmed/32053351 http://dx.doi.org/10.1021/acs.inorgchem.9b03613 |