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Orthogonal Coordination Chemistry of PTA toward Ru(II) and Zn(II) (PTA = 1,3,5-Triaza-7-phosphaadamantane) for the Construction of 1D and 2D Metal-Mediated Porphyrin Networks

[Image: see text] This work demonstrates that PTA (1,3,5-triaza-7-phosphaadamantane) behaves as an orthogonal ligand between Ru(II) and Zn(II), since it selectively binds through the P atom to ruthenium and through one or more of the N atoms to zinc. This property of PTA was exploited for preparing...

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Detalles Bibliográficos
Autores principales: Battistin, Federica, Vidal, Alessio, Cavigli, Paolo, Balducci, Gabriele, Iengo, Elisabetta, Alessio, Enzo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997375/
https://www.ncbi.nlm.nih.gov/pubmed/32100542
http://dx.doi.org/10.1021/acs.inorgchem.0c00080