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Reactivity Trends of Lewis Acidic Sites in Methylaluminoxane and Some of Its Modifications

[Image: see text] The established model cluster (AlOMe)(16)(AlMe(3))(6) for methylaluminoxane (MAO) cocatalyst has been studied by density functional theory, aiming to rationalize the different behaviors of unmodified MAO and TMA-depleted MAO/BHT (TMA = trimethylaluminum; BHT = 2,6-di-tert-butyl-4-m...

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Detalles Bibliográficos
Autores principales: Zaccaria, Francesco, Budzelaar, Peter H. M., Cipullo, Roberta, Zuccaccia, Cristiano, Macchioni, Alceo, Busico, Vincenzo, Ehm, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7997381/
https://www.ncbi.nlm.nih.gov/pubmed/32271565
http://dx.doi.org/10.1021/acs.inorgchem.0c00533