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Polymerization Isomerism in Co-M (M = Cu, Ag, Au) Carbonyl Clusters: Synthesis, Structures and Computational Investigation

The reaction of [Co(CO)(4)](−) (1) with M(I) compounds (M = Cu, Ag, Au) was reinvestigated unraveling an unprecedented case of polymerization isomerism. Thus, as previously reported, the trinuclear clusters [M{Co(CO)(4)}(2)](−) (M = Cu, 2; Ag, 3; Au, 4) were obtained by reacting 1 with M(I) in a 2:1...

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Detalles Bibliográficos
Autores principales: Cesari, Cristiana, Berti, Beatrice, Calcagno, Francesco, Femoni, Cristina, Garavelli, Marco, Iapalucci, Maria Carmela, Rivalta, Ivan, Zacchini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7998641/
https://www.ncbi.nlm.nih.gov/pubmed/33799629
http://dx.doi.org/10.3390/molecules26061529