Rate Dependence on Inductive and Resonance Effects for the Organocatalyzed Enantioselective Conjugate Addition of Alkenyl and Alkynyl Boronic Acids to β-Indolyl Enones and β-Pyrrolyl Enones

Two key factors bear on reaction rates for the conjugate addition of alkenyl boronic acids to heteroaryl-appended enones: the proximity of inductively electron-withdrawing heteroatoms to the site of bond formation and the resonance contribution of available heteroatom lone pairs to stabilize the dev...

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Detalles Bibliográficos
Autores principales: Boylan, Amy, Nguyen, Thien S., Lundy, Brian J., Li, Jian-Yuan, Vallakati, Ravikrishna, Sundstrom, Sasha, May, Jeremy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8000498/
https://www.ncbi.nlm.nih.gov/pubmed/33799473
http://dx.doi.org/10.3390/molecules26061615

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8000498/
https://www.ncbi.nlm.nih.gov/pubmed/33799473
http://dx.doi.org/10.3390/molecules26061615

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