Direct Metal-Free Transformation of Alkynes to Nitriles: Computational Evidence for the Precise Reaction Mechanism

Density functional theory calculations elucidated the precise reaction mechanism for the conversion of diphenylacetylenes into benzonitriles involving the cleavage of the triple C≡C bond, with N-iodosuccinimide (NIS) as an oxidant and trimethylsilyl azide (TMSN(3)) as a nitrogen donor. The reaction...

Descripción completa

Detalles Bibliográficos
Autores principales: Hok, Lucija, Vianello, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8004279/
https://www.ncbi.nlm.nih.gov/pubmed/33801102
http://dx.doi.org/10.3390/ijms22063193

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8004279/
https://www.ncbi.nlm.nih.gov/pubmed/33801102
http://dx.doi.org/10.3390/ijms22063193

Ejemplares similares