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Direct Metal-Free Transformation of Alkynes to Nitriles: Computational Evidence for the Precise Reaction Mechanism

Density functional theory calculations elucidated the precise reaction mechanism for the conversion of diphenylacetylenes into benzonitriles involving the cleavage of the triple C≡C bond, with N-iodosuccinimide (NIS) as an oxidant and trimethylsilyl azide (TMSN(3)) as a nitrogen donor. The reaction...

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Detalles Bibliográficos
Autores principales:	Hok, Lucija, Vianello, Robert
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8004279/ https://www.ncbi.nlm.nih.gov/pubmed/33801102 http://dx.doi.org/10.3390/ijms22063193

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