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Electric-Field-Induced Second Harmonic Generation Nonlinear Optic Response of A(4) β-Pyrrolic-Substituted Zn(II) Porphyrins: When Cubic Contributions Cannot Be Neglected
[Image: see text] In this work, we have prepared a series of A(4) Zn(II) porphyrins, carrying in the β-pyrrolic-position one or two π-delocalized ethynylphenyl moieties with a −NO(2) acceptor or a −NMe(2) donor pendant, and measured their second-order NLO response in CHCl(3) solution at 1907 nm via...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8007098/ https://www.ncbi.nlm.nih.gov/pubmed/32412749 http://dx.doi.org/10.1021/acs.inorgchem.0c00451 |