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Direct Mechanistic Evidence for a Nonheme Complex Reaction through a Multivariate XAS Analysis
[Image: see text] In this work, we propose a method to directly determine the mechanism of the reaction between the nonheme complex Fe(II)(tris(2-pyridylmethyl)amine) ([Fe(II)(TPA)(CH(3)CN)(2)](2+)) and peracetic acid (AcOOH) in CH(3)CN, working at room temperature. A multivariate analysis is applie...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8008396/ https://www.ncbi.nlm.nih.gov/pubmed/32598841 http://dx.doi.org/10.1021/acs.inorgchem.0c01132 |