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Direct Mechanistic Evidence for a Nonheme Complex Reaction through a Multivariate XAS Analysis

[Image: see text] In this work, we propose a method to directly determine the mechanism of the reaction between the nonheme complex Fe(II)(tris(2-pyridylmethyl)amine) ([Fe(II)(TPA)(CH(3)CN)(2)](2+)) and peracetic acid (AcOOH) in CH(3)CN, working at room temperature. A multivariate analysis is applie...

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Detalles Bibliográficos
Autores principales: Tavani, Francesco, Martini, Andrea, Capocasa, Giorgio, Di Stefano, Stefano, Lanzalunga, Osvaldo, D’Angelo, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8008396/
https://www.ncbi.nlm.nih.gov/pubmed/32598841
http://dx.doi.org/10.1021/acs.inorgchem.0c01132