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Antimony–Oxo Porphyrins as Photocatalysts for Redox-Neutral C–H to C–C Bond Conversion
[Image: see text] The use of high-valent antimony–oxo porphyrins as visible-light photocatalysts operating via direct hydrogen atom transfer has been demonstrated. Computational analysis indicates that the triplet excited state of these complexes shows an oxyl radical behavior, while the Sb(V) cente...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8009479/ https://www.ncbi.nlm.nih.gov/pubmed/33815891 http://dx.doi.org/10.1021/acscatal.0c02250 |