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Antimony–Oxo Porphyrins as Photocatalysts for Redox-Neutral C–H to C–C Bond Conversion

[Image: see text] The use of high-valent antimony–oxo porphyrins as visible-light photocatalysts operating via direct hydrogen atom transfer has been demonstrated. Computational analysis indicates that the triplet excited state of these complexes shows an oxyl radical behavior, while the Sb(V) cente...

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Detalles Bibliográficos
Autores principales:	Capaldo, Luca, Ertl, Martin, Fagnoni, Maurizio, Knör, Günther, Ravelli, Davide
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8009479/ https://www.ncbi.nlm.nih.gov/pubmed/33815891 http://dx.doi.org/10.1021/acscatal.0c02250

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