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An In-Depth Computational Study of Alkene Cyclopropanation Catalyzed by Fe(porphyrin)(OCH(3)) Complexes. The Environmental Effects on the Energy Barriers
[Image: see text] Iron porphyrin methoxy complexes, of the general formula [Fe(porphyrin)(OCH(3))], are able to catalyze the reaction of diazo compounds with alkenes to give cyclopropane products with very high efficiency and selectivity. The overall mechanism of these reactions was thoroughly inves...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8009515/ https://www.ncbi.nlm.nih.gov/pubmed/32799510 http://dx.doi.org/10.1021/acs.inorgchem.0c00912 |