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Direct 1,1-Bisphosphonation of Isocyanides: Atom- and Step-Economical Access to Bisphosphinoylaminomethanes

[Image: see text] An atom- and step-economical strategy for the synthesis of bisphosphinoylaminomethanes is reported. This metal-free bisphosphinylation reaction proceeded smoothly through a base-mediated direct 1,1-bisphosphonation of phosphine oxides and isocyanides under mild conditions. The pres...

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Detalles Bibliográficos
Autores principales: Yuan, Qing, Liu, Hua-Wei, Cai, Zhong-Jian, Ji, Shun-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015124/
https://www.ncbi.nlm.nih.gov/pubmed/33817511
http://dx.doi.org/10.1021/acsomega.1c00160