Structural Diversity in Molecular Nickel Phosphide Carbonyl Nanoclusters

[Image: see text] The reaction of [Ni(6)(CO)(12)](2–) as a [NBu(4)](+) salt in CH(2)Cl(2) with 0.8 equiv of PCl(3) afforded [Ni(14)P(2)(CO)(22)](2–). In contrast, the reactions of [Ni(6)(CO)(12)](2–) as a [NEt(4)](+) salt with 0.4–0.5 equiv of POCl(3) afforded [Ni(22–x)P(2)(CO)(29–x)](4–) (x = 0.84)...

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Detalles Bibliográficos
Autores principales: Capacci, Chiara, Cesari, Cristiana, Femoni, Cristina, Iapalucci, Maria Carmela, Mancini, Federica, Ruggieri, Silvia, Zacchini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015230/
https://www.ncbi.nlm.nih.gov/pubmed/33086004
http://dx.doi.org/10.1021/acs.inorgchem.0c02572

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015230/
https://www.ncbi.nlm.nih.gov/pubmed/33086004
http://dx.doi.org/10.1021/acs.inorgchem.0c02572

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