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Structural Diversity in Molecular Nickel Phosphide Carbonyl Nanoclusters
[Image: see text] The reaction of [Ni(6)(CO)(12)](2–) as a [NBu(4)](+) salt in CH(2)Cl(2) with 0.8 equiv of PCl(3) afforded [Ni(14)P(2)(CO)(22)](2–). In contrast, the reactions of [Ni(6)(CO)(12)](2–) as a [NEt(4)](+) salt with 0.4–0.5 equiv of POCl(3) afforded [Ni(22–x)P(2)(CO)(29–x)](4–) (x = 0.84)...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8015230/ https://www.ncbi.nlm.nih.gov/pubmed/33086004 http://dx.doi.org/10.1021/acs.inorgchem.0c02572 |