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Basicity-Tuned Reactivity: diaza-[1,2]-Wittig versus diaza-[1,3]-Wittig Rearrangements of 3,4-Dihydro-2H-1,2,3-benzothiadiazine 1,1-Dioxides

[Image: see text] The base-induced (t-BuOK) rearrangement reactions of 3,4-dihydro-2H-1,2,3-benzothiadiazine 1,1-dioxides result in a ring opening along the N–N bond, followed by ring closure with the formation of new C–N bonds. The position of the newly formed C–N bond can selectively be tuned by t...

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Detalles Bibliográficos
Autores principales: Gyűjtő, Imre, Porcs-Makkay, Márta, Szabó, Gergő, Kelemen, Zsolt, Pusztai, Gyöngyvér, Tóth, Gábor, Dancsó, András, Halász, Judit, Simig, Gyula, Volk, Balázs, Nyulászi, László
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8021225/
https://www.ncbi.nlm.nih.gov/pubmed/33382258
http://dx.doi.org/10.1021/acs.joc.0c02512