Cargando…

The Chemistry of Short-Lived α-Fluorocarbocations

[Image: see text] The present study of the chemistry of short-lived α-fluorocarbocations reveals that even inactive methyl carbons can serve as nucleophiles, attacking a cationic center. This, in turn, facilitates the synthesis of a cyclopropane ring in certain triterpene backbones. We report the sy...

Descripción completa

Detalles Bibliográficos
Autores principales: Rozen, Shlomo, Vints, Inna, Lerner, Ana, Hod, Oded, Brothers, Edward N., Moncho, Salvador
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8023664/
https://www.ncbi.nlm.nih.gov/pubmed/33615796
http://dx.doi.org/10.1021/acs.joc.0c02731