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The Chemistry of Short-Lived α-Fluorocarbocations
[Image: see text] The present study of the chemistry of short-lived α-fluorocarbocations reveals that even inactive methyl carbons can serve as nucleophiles, attacking a cationic center. This, in turn, facilitates the synthesis of a cyclopropane ring in certain triterpene backbones. We report the sy...
Autores principales: | Rozen, Shlomo, Vints, Inna, Lerner, Ana, Hod, Oded, Brothers, Edward N., Moncho, Salvador |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8023664/ https://www.ncbi.nlm.nih.gov/pubmed/33615796 http://dx.doi.org/10.1021/acs.joc.0c02731 |
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