SmI(2)-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity

[Image: see text] The archetypal single electron transfer reductant, samarium(II) diiodide (SmI(2), Kagan’s reagent), remains one of the most important reducing agents and mediators of radical chemistry after four decades of widespread use in synthesis. While the chemistry of SmI(2) is very often un...

Descripción completa

Detalles Bibliográficos
Autores principales: Agasti, Soumitra, Beattie, Nicholas A., McDouall, Joseph J. W., Procter, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028054/
https://www.ncbi.nlm.nih.gov/pubmed/33629852
http://dx.doi.org/10.1021/jacs.1c01356

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028054/
https://www.ncbi.nlm.nih.gov/pubmed/33629852
http://dx.doi.org/10.1021/jacs.1c01356

Ejemplares similares