Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer

Controlling the reactivity of reactive intermediates is essential to achieve selective transformations. Due to the facile 1,5-hydrogen atom transfer (HAT), alkoxyl radicals have been proven to be important synthetic intermediates for the δ-functionalization of alcohols. Herein, we disclose a strateg...

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Detalles Bibliográficos
Autores principales: Yang, Zhaoliang, Niu, Yunhong, He, Xiaoqian, Chen, Suo, Liu, Shanshan, Li, Zhengyu, Chen, Xiang, Zhang, Yunxiao, Lan, Yu, Shen, Xiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8035221/
https://www.ncbi.nlm.nih.gov/pubmed/33837201
http://dx.doi.org/10.1038/s41467-021-22382-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8035221/
https://www.ncbi.nlm.nih.gov/pubmed/33837201
http://dx.doi.org/10.1038/s41467-021-22382-y

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