Cargando…

Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer

Controlling the reactivity of reactive intermediates is essential to achieve selective transformations. Due to the facile 1,5-hydrogen atom transfer (HAT), alkoxyl radicals have been proven to be important synthetic intermediates for the δ-functionalization of alcohols. Herein, we disclose a strateg...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yang, Zhaoliang, Niu, Yunhong, He, Xiaoqian, Chen, Suo, Liu, Shanshan, Li, Zhengyu, Chen, Xiang, Zhang, Yunxiao, Lan, Yu, Shen, Xiao
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8035221/ https://www.ncbi.nlm.nih.gov/pubmed/33837201 http://dx.doi.org/10.1038/s41467-021-22382-y

Ejemplares similares

FLP‐Catalyzed Transfer Hydrogenation of Silyl Enol Ethers
por: Khan, Imtiaz, et al.
Publicado: (2018)

Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
por: Papadakis, Raffaello, et al.
Publicado: (2016)

Radical cascade synthesis of azoles via tandem hydrogen atom transfer
por: Chen, Andrew D., et al.
Publicado: (2020)

Alcohols as Substrates and Solvents for the Construction of 3-Alkoxylated-2-Oxindoles by Direct Alkoxylation of 3-Halooxindoles
por: Lin, Bing, et al.
Publicado: (2017)

Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives
por: Han, Jiao-Na, et al.
Publicado: (2018)

Catalytic Synthesis of Indolines by Hydrogen Atom Transfer to Cobalt(III)–Carbene Radicals
por: Karns, Alexander S., et al.
Publicado: (2017)

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals
por: Shevick, Sophia L., et al.
Publicado: (2020)

Synthesis and Cytotoxic Evaluation of Alkoxylated Chalcones
por: Bai, Xiao-Guang, et al.
Publicado: (2014)

Stereoselective hydrogen atom transfer to acyclic radicals: a switch enabling diastereodivergent borylative radical cascades
por: Ye, Tian, et al.
Publicado: (2022)

Reversible Activation and Transfer of White Phosphorus by Silyl‐Stannylene
por: Sarkar, Debotra, et al.
Publicado: (2020)

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
por: Romero, R. Martin, et al.
Publicado: (2022)

Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation
por: Zhang, Jing, et al.
Publicado: (2019)

C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals
por: Sarkar, Sumon, et al.
Publicado: (2020)

Characterization and Fate of Hydrogen-Bonded Free-Radical Intermediates and Their Coupling Products from the Hydrogen Atom Transfer Agent 1,8-Naphthalenediol
por: Manini, Paola, et al.
Publicado: (2018)

Enhanced and Tunable Electrorheological Capability using Surface Initiated Atom Transfer Radical Polymerization Modification with Simultaneous Reduction of the Graphene Oxide by Silyl-Based Polymer Grafting
por: Kutalkova, Erika, et al.
Publicado: (2019)

Atom Transfer Radical Polymerization in the Solid‐State
por: Cho, Hong Y., et al.
Publicado: (2020)

Iron Catalysts in Atom Transfer Radical Polymerization
por: Dadashi-Silab, Sajjad, et al.
Publicado: (2020)

Characterization of a Ferryl Flip in Electronically Tuned Nonheme Complexes. Consequences in Hydrogen Atom Transfer Reactivity
por: Dantignana, Valeria, et al.
Publicado: (2022)

Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand
por: Zhang, Peng, et al.
Publicado: (2018)

The hydrogen atom transfer reactivity of sulfinic acids
por: Griesser, Markus, et al.
Publicado: (2018)

Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes
por: Zhou, Jun, et al.
Publicado: (2023)

Phospholipid peroxidation-driven modification of chondrogenic transcription factor mediates alkoxyl radicals-induced impairment of embryonic bone development
por: Niu, Jie, et al.
Publicado: (2022)

Electrochemical activation of C–H by electron-deficient W(2)C nanocrystals for simultaneous alkoxylation and hydrogen evolution
por: Lin, Xiu, et al.
Publicado: (2021)

Alkane Desaturation via Concerted Double Hydrogen Atom Transfer to Benzyne
por: Niu, Dawen, et al.
Publicado: (2013)

Development of Environmentally Friendly Atom Transfer Radical Polymerization
por: Yuan, Ming, et al.
Publicado: (2020)

Ultrasound-Mediated Atom Transfer Radical Polymerization (ATRP)
por: Zaborniak, Izabela, et al.
Publicado: (2019)

Aqueous electrochemically-triggered atom transfer radical polymerization
por: Zhao, Boyu, et al.
Publicado: (2022)

Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes
por: Wang, Dinghai, et al.
Publicado: (2021)

Influence of an Alkoxylation Grade of Acrylates on Shrinkage of UV-Curable Compositions
por: Czech, Zbigniew, et al.
Publicado: (2020)

Photoinitiated Multicomponent Anti-Markovnikov Alkoxylation over Graphene Oxide
por: Nie, Liang, et al.
Publicado: (2022)

Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand
por: Spasyuk, Denis M., et al.
Publicado: (2016)

Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
por: Chen, Xiang, et al.
Publicado: (2020)

Radical zinc-atom-transfer-based carbozincation of haloalkynes with dialkylzincs
por: Chemla, Fabrice, et al.
Publicado: (2013)

Engineered myoglobin as a catalyst for atom transfer radical cyclisation
por: Lubskyy, Andriy, et al.
Publicado: (2022)

Electrochemical Investigation of Iron-Catalyzed Atom Transfer Radical Polymerization
por: Gazzola, Gianluca, et al.
Publicado: (2022)

Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon
por: Wu, Ya, et al.
Publicado: (2019)

Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization
por: Asgari, Parham, et al.
Publicado: (2019)

Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides
por: Proctor, Rupert S. J., et al.
Publicado: (2021)

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation
por: Capaldo, Luca, et al.
Publicado: (2021)

Rapid Iron(III)−Fluoride‐Mediated Hydrogen Atom Transfer
por: Panda, Chakadola, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_k0ei8nomf6j21345dv8ui4joe6