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Isomerization of 5-(2H-Azirin-2-yl)oxazoles: An Atom-Economic Approach to 4H-Pyrrolo[2,3-d]oxazoles

An atom economical method for the preparation of variously substituted 4H-pyrrolo[2,3-d]oxazoles was developed on the basis of thermal isomerization of 5-(2H-azirin-2-yl)oxazoles. The latter were prepared by Rh(2)(oct)(4) catalyzed reaction of 2-(3-aryl/heteroaryl)-2-diazoacetyl-2H-azirines with a s...

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Detalles Bibliográficos
Autores principales: Zanakhov, Timur O., Galenko, Ekaterina E., Kryukova, Mariya A., Novikov, Mikhail S., Khlebnikov, Alexander A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8036974/
https://www.ncbi.nlm.nih.gov/pubmed/33810476
http://dx.doi.org/10.3390/molecules26071881