Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis

A new class of bis-cyclometalated iridium(III) catalysts containing two inert cyclometalated 6-tert-butyl-2-phenyl-2H-indazole bidentate ligands or two inert cyclometalated 5-tert-butyl-1-methyl-2-phenylbenzimidazoles is introduced. The coordination sphere is complemented by two labile acetonitriles...

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Detalles Bibliográficos
Autores principales: Brunen, Sebastian, Grell, Yvonne, Steinlandt, Philipp S., Harms, Klaus, Meggers, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8037582/
https://www.ncbi.nlm.nih.gov/pubmed/33804954
http://dx.doi.org/10.3390/molecules26071822

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8037582/
https://www.ncbi.nlm.nih.gov/pubmed/33804954
http://dx.doi.org/10.3390/molecules26071822

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