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An Excess Electron Bound to Magnesium Halides and Basic Grignard Compounds (RMgX and RMgR, R = Me, Et, Ph; X = F, Cl, Br)

[Image: see text] Grignard reagents are commonly used in organic synthesis, yet their ability to form stable anionic states has not been recognized thus far. In this work, representative examples of RMgF, RMgCl, and RMgBr molecules involving methyl, ethyl, and phenyl functional groups serving as R s...

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Detalles Bibliográficos
Autores principales: Brzeski, Jakub, Freza, Sylwia, Czapla, Marcin, Skurski, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8041300/
https://www.ncbi.nlm.nih.gov/pubmed/33689341
http://dx.doi.org/10.1021/acs.jpca.1c00750