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Tenfold Metalation of Ferrocene: Synthesis, Structures, and Metallophilic Interactions in FeC(10)(HgX)(10)

The permercuration of ferrocene was achieved by reacting ferrocene with 10 equivalents of mercury(II) butyrate Hg(O(2)CC(3)H(7))(2) in a facile one‐pot reaction in multi‐gram scale and high yields. The butyrate groups in FeC(10)(HgX)(10) (X=O(2)CC(3)H(7)) can be exchanged by treatment with trifluoro...

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Detalles Bibliográficos
Autores principales: Rupf, Susanne Margot, Schröder, Gabriel, Sievers, Robin, Malischewski, Moritz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048484/
https://www.ncbi.nlm.nih.gov/pubmed/33492692
http://dx.doi.org/10.1002/chem.202100261