Divergent Carbocatalytic Routes in Oxidative Coupling of Benzofused Heteroaryl Dimers: A Mechanistic Update

Mildly thermal air or HNO(3) oxidized activated carbons catalyse oxidative dehydrogenative couplings of benzo[b]fused heteroaryl 2,2’‐dimers, e.g., 2‐(benzofuran‐2‐yl)‐1H‐indole, to chiral 3,3’‐coupled cyclooctatetraenes or carbazole‐type migrative products under O(2) atmosphere. DFT calculations sh...

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Detalles Bibliográficos
Autores principales: Casadio, David S., Aikonen, Santeri, Lenarda, Anna, Nieger, Martin, Hu, Tao, Taubert, Stefan, Sundholm, Dage, Muuronen, Mikko, Wirtanen, Tom, Helaja, Juho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048508/
https://www.ncbi.nlm.nih.gov/pubmed/33427343
http://dx.doi.org/10.1002/chem.202005433

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048508/
https://www.ncbi.nlm.nih.gov/pubmed/33427343
http://dx.doi.org/10.1002/chem.202005433

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