A Molecular Low‐Coordinate [Fe‐S‐Fe] Unit in Three Oxidation States

A [Fe‐S‐Fe] subunit with a single sulfide bridging two low‐coordinate iron ions is the supposed active site of the iron‐molybdenum co‐factor (FeMoco) of nitrogenase. Here we report a dinuclear monosulfido bridged diiron(II) complex with a similar complex geometry that can be oxidized stepwise to dii...

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Detalles Bibliográficos
Autores principales: Schneider, Christian, Demeshko, Serhiy, Meyer, Franc, Werncke, C. Gunnar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048577/
https://www.ncbi.nlm.nih.gov/pubmed/33512018
http://dx.doi.org/10.1002/chem.202100336

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048577/
https://www.ncbi.nlm.nih.gov/pubmed/33512018
http://dx.doi.org/10.1002/chem.202100336

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