Tuning the H‐Atom Transfer Reactivity of Iron(IV)‐Oxo Complexes as Probed by Infrared Photodissociation Spectroscopy

Reactivities of non‐heme iron(IV)‐oxo complexes are mostly controlled by the ligands. Complexes with tetradentate ligands such as [(TPA)FeO](2+) (TPA=tris(2‐pyridylmethyl)amine) belong to the most reactive ones. Here, we show a fine‐tuning of the reactivity of [(TPA)FeO](2+) by an additional ligand...

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Detalles Bibliográficos
Autores principales: Tripodi, Guilherme L., Dekker, Magda M. J., Roithová, Jana, Que, Lawrence
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048595/
https://www.ncbi.nlm.nih.gov/pubmed/33393186
http://dx.doi.org/10.1002/anie.202016695

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048595/
https://www.ncbi.nlm.nih.gov/pubmed/33393186
http://dx.doi.org/10.1002/anie.202016695

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