Cu(OTf)(2)‐Mediated Cross‐Coupling of Nitriles and N‐Heterocycles with Arylboronic Acids to Generate Nitrilium and Pyridinium Products

Metal‐catalyzed C–N cross‐coupling generally forms C−N bonds by reductive elimination from metal complexes bearing covalent C‐ and N‐ligands. We have identified a Cu‐mediated C–N cross‐coupling that uses a dative N‐ligand in the bond‐forming event, which, in contrast to conventional methods, generat...

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Detalles Bibliográficos
Autores principales: Bell, Nicola L., Xu, Chao, Fyfe, James W. B., Vantourout, Julien C., Brals, Jeremy, Chabbra, Sonia, Bode, Bela E., Cordes, David B., Slawin, Alexandra M. Z., McGuire, Thomas M., Watson, Allan J. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048606/
https://www.ncbi.nlm.nih.gov/pubmed/33449408
http://dx.doi.org/10.1002/anie.202016811

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048606/
https://www.ncbi.nlm.nih.gov/pubmed/33449408
http://dx.doi.org/10.1002/anie.202016811

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