A New Type of Supramolecular Fluid Based on H(2)O–Alkylammonium/Phosphonium Solutions

Here we show that by adjusting the concentration of tetrabutyl ammonium and phosphonium salts in water (≈1.5–2.0 m), hydrophobic solvation triggers the formation of a unique, highly incompressible supramolecular liquid, with a dynamic structure similar to clathrates, involving essentially all H(2)O...

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Detalles Bibliográficos
Autores principales: López‐Bueno, Carlos, Herreros‐Lucas, Carlos, Suárez‐Rodríguez, Manuel, Bittermann, Marius R., Amigo, Alfredo, Woutersen, Sander, Giménez‐López, María, Rivadulla, Francisco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048622/
https://www.ncbi.nlm.nih.gov/pubmed/33416197
http://dx.doi.org/10.1002/anie.202015800

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048622/
https://www.ncbi.nlm.nih.gov/pubmed/33416197
http://dx.doi.org/10.1002/anie.202015800

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