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A New Type of Supramolecular Fluid Based on H(2)O–Alkylammonium/Phosphonium Solutions
Here we show that by adjusting the concentration of tetrabutyl ammonium and phosphonium salts in water (≈1.5–2.0 m), hydrophobic solvation triggers the formation of a unique, highly incompressible supramolecular liquid, with a dynamic structure similar to clathrates, involving essentially all H(2)O...
Autores principales: | López‐Bueno, Carlos, Herreros‐Lucas, Carlos, Suárez‐Rodríguez, Manuel, Bittermann, Marius R., Amigo, Alfredo, Woutersen, Sander, Giménez‐López, María, Rivadulla, Francisco |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048622/ https://www.ncbi.nlm.nih.gov/pubmed/33416197 http://dx.doi.org/10.1002/anie.202015800 |
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