Reactions of B(2)(o‐tolyl)(4) with Boranes: Assembly of the Pentaborane(9), HB[B(o‐tolyl)(μ‐H)](4)

Reactions of the diborane(4) B(2)(o‐tolyl)(4) and monohydridoboranes are shown to give B(o‐tolyl)(3) and (o‐tolyl)BR(2) (R(2)=(C(8)H(14)) 3, cat 4, pin 5, (C(6)F(5))(2) 6) as the major products. The corresponding reaction with BH(3)‐sources gives complex mixtures, resulting from hydride/aryl exchang...

Descripción completa

Detalles Bibliográficos
Autores principales: Bamford, Karlee L., Qu, Zheng‐Wang, Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048642/
https://www.ncbi.nlm.nih.gov/pubmed/33539608
http://dx.doi.org/10.1002/anie.202101054

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048642/
https://www.ncbi.nlm.nih.gov/pubmed/33539608
http://dx.doi.org/10.1002/anie.202101054

Ejemplares similares