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Reactions of B(2)(o‐tolyl)(4) with Boranes: Assembly of the Pentaborane(9), HB[B(o‐tolyl)(μ‐H)](4)
Reactions of the diborane(4) B(2)(o‐tolyl)(4) and monohydridoboranes are shown to give B(o‐tolyl)(3) and (o‐tolyl)BR(2) (R(2)=(C(8)H(14)) 3, cat 4, pin 5, (C(6)F(5))(2) 6) as the major products. The corresponding reaction with BH(3)‐sources gives complex mixtures, resulting from hydride/aryl exchang...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048642/ https://www.ncbi.nlm.nih.gov/pubmed/33539608 http://dx.doi.org/10.1002/anie.202101054 |