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Spin–Electric Coupling in a Cobalt(II)‐Based Spin Triangle Revealed by Electric‐Field‐Modulated Electron Spin Resonance Spectroscopy

A cobalt(II)‐based spin triangle shows a significant spin–electric coupling. [Co(3)(pytag)(py)(6)Cl(3)]ClO(4)⋅3 py crystallizes in the acentric monoclinic space group P2(1). The intra‐triangle antiferromagnetic interaction, of the order of ca. −15 cm(−1) (H=−JS(a)S(b)), leads to spin frustration. Th...

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Detalles Bibliográficos
Autores principales: Kintzel, Benjamin, Fittipaldi, Maria, Böhme, Michael, Cini, Alberto, Tesi, Lorenzo, Buchholz, Axel, Sessoli, Roberta, Plass, Winfried
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048656/
https://www.ncbi.nlm.nih.gov/pubmed/33511751
http://dx.doi.org/10.1002/anie.202017116