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Silver‐Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions

An enantioselective sulfimidation of 3‐thiosubstituted 2‐quinolones and 2‐pyridones was achieved with a stoichiometric nitrene source (PhI=NNs) and a silver‐based catalyst system. Key to the success of the reaction is the use of a chiral phenanthroline ligand with a hydrogen bonding site. The enanti...

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Detalles Bibliográficos
Autores principales: Annapureddy, Rajasekar Reddy, Burg, Finn, Gramüller, Johannes, Golub, Tino P., Merten, Christian, Huber, Stefan M., Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048691/
https://www.ncbi.nlm.nih.gov/pubmed/33438798
http://dx.doi.org/10.1002/anie.202016561