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Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
Metalloradicals are key species in synthesis, catalysis, and bioinorganic chemistry. Herein, two iron radical cation complexes (3‐E)GaCl(4) [(3‐E)(.+) = [{(IPr)C(Ph)E}(2)Fe(CO)(3)](.+), E = P or As; IPr = C{(NDipp)CH}(2), Dipp = 2,6‐iPr(2)C(6)H(3)] are reported as crystalline solids. Treatment of th...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048781/ https://www.ncbi.nlm.nih.gov/pubmed/33470468 http://dx.doi.org/10.1002/chem.202100213 |