Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand

We present the synthesis and coordination chemistry of a bulky, tripodal N,N,O ligand, Im(Ph2)NNO (tBu) (L), designed to model the 2‐His‐1‐carboxylate facial triad (2H1C) by means of two imidazole groups and an anionic 2,4‐di‐tert‐butyl‐subtituted phenolate. Reacting K‐L with MCl(2) (M = Fe, Zn) aff...

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Detalles Bibliográficos
Autores principales: Monkcom, Emily C., de Bruin, Daniël, de Vries, Annemiek J., Lutz, Martin, Ye, Shengfa, Klein Gebbink, Robertus J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048785/
https://www.ncbi.nlm.nih.gov/pubmed/33326655
http://dx.doi.org/10.1002/chem.202004633

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048785/
https://www.ncbi.nlm.nih.gov/pubmed/33326655
http://dx.doi.org/10.1002/chem.202004633

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