Cargando…

Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand

We present the synthesis and coordination chemistry of a bulky, tripodal N,N,O ligand, Im(Ph2)NNO (tBu) (L), designed to model the 2‐His‐1‐carboxylate facial triad (2H1C) by means of two imidazole groups and an anionic 2,4‐di‐tert‐butyl‐subtituted phenolate. Reacting K‐L with MCl(2) (M = Fe, Zn) aff...

Descripción completa

Detalles Bibliográficos
Autores principales:	Monkcom, Emily C., de Bruin, Daniël, de Vries, Annemiek J., Lutz, Martin, Ye, Shengfa, Klein Gebbink, Robertus J. M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048785/ https://www.ncbi.nlm.nih.gov/pubmed/33326655 http://dx.doi.org/10.1002/chem.202004633

Ejemplares similares

An artificial metallolyase with pliable 2-His-1-carboxylate facial triad for stereoselective Michael addition
por: Matsumoto, Ryusei, et al.
Publicado: (2023)

Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II)
por: Riemersma, Charl F., et al.
Publicado: (2019)

Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate
por: Bruijnincx, Pieter C. A., et al.
Publicado: (2007)

Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
por: Collado, Alba, et al.
Publicado: (2015)

How bulky ligands control the chemoselectivity of Pd-catalyzed N-arylation of ammonia
por: Kim, Seoung-Tae, et al.
Publicado: (2019)

Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes
por: van Beek, Cody B., et al.
Publicado: (2022)

Unsymmetric N-heterocyclic carbene ligand enabled nickel-catalysed arylation of bulky primary and secondary amines
por: Wang, Zi-Chao, et al.
Publicado: (2023)

1,2‐Addition of Diethylzinc to a Bis(Imidazolyl)ketone Ligand
por: Folkertsma, Emma, et al.
Publicado: (2018)

Copper-Catalyzed N-Arylation of Amides Using (S)-N-Methylpyrrolidine-2-carboxylate as the Ligand
por: Wang, Chaoyu, et al.
Publicado: (2010)

Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6‐Diisopropyl‐N‐(trimethylsilyl)anilide Ligands
por: Maddock, Lewis C. H., et al.
Publicado: (2021)

Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H(2) Formation
por: Ghosh, Pradip, et al.
Publicado: (2020)

Near quantitative synthesis of urea macrocycles enabled by bulky N-substituent
por: Yang, Yingfeng, et al.
Publicado: (2021)

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6‐Diisopropyl‐N‐(trimethylsilyl)anilino Ligand
por: Fuentes, M. Ángeles, et al.
Publicado: (2016)

Synthesis of amino acids and peptides with bulky side chains via ligand-enabled carboxylate-directed γ-C(sp(3))–H arylation
por: Liu, Lei, et al.
Publicado: (2019)

Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents
por: Yu, Craig P., et al.
Publicado: (2021)

A Cp(tt)‐Based Trioxo‐Rhenium Catalyst for the Deoxydehydration of Diols and Polyols
por: Li, Jing, et al.
Publicado: (2018)

Direct Addition of Grignard Reagents to Aliphatic Carboxylic Acids Enabled by Bulky turbo‐Organomagnesium Anilides
por: Colas, Kilian, et al.
Publicado: (2022)

The Nϵ‐Rule for Serine, but Not Cysteine Catalytic Triads
por: Czapinska, Honorata, et al.
Publicado: (2022)

Gradenigo's Syndrome: Beyond the Classical Triad of Diplopia, Facial Pain and Otorrhea
por: Pedroso, José Luiz, et al.
Publicado: (2011)

Cyclooctatetraenide-based single-ion magnets featuring bulky cyclopentadienyl ligand
por: Korzyński, Maciej Damian, et al.
Publicado: (2022)

A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents
por: Grieco, Gabriele, et al.
Publicado: (2015)

Impact of bulky phenylalkyl substituents on the air-stable n-channel transistors of birhodanine analogues
por: Iijima, Kodai, et al.
Publicado: (2018)

The Role of Tyr-His-Trp Triad and Water Molecule Near the N1-Atom of 2-Hydroperoxycoelenterazine in Bioluminescence of Hydromedusan Photoproteins: Structural and Mutagenesis Study
por: Natashin, Pavel V., et al.
Publicado: (2023)

Antibacterial and Antifungal Activity of Zinc(II) Carboxylates With/Without N-Donor Organic Ligands
por: Zelenák, V., et al.
Publicado: (2002)

Supramolecular Immobilization of Adamantyl and Carboxylate Modified N-Heterocyclic Carbene Ligand on Cucurbituril Substrates
por: Keita, Hamidou
Publicado: (2022)

Ultra-small palladium nano-particles synthesized using bulky S/Se and N donor ligands as a stabilizer: application as catalysts for Suzuki–Miyaura coupling
por: Oswal, Preeti, et al.
Publicado: (2019)

Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform
por: Kurup, Sudheer S., et al.
Publicado: (2022)

A Plausible Mechanism for the Iridium-Catalyzed Hydrogenation of a Bulky N-Aryl Imine in the (S)-Metolachlor Process
por: Kwan, Amanda L., et al.
Publicado: (2022)

Rational Design of a Facially Coordinating P,N,N Ligand for Manganese‐Catalysed Enantioselective Hydrogenation of Cyclic Ketones
por: Oates, Conor L., et al.
Publicado: (2022)

Aziridination Reactivity of a Manganese(II) Complex with a Bulky Chelating Bis(Alkoxide) Ligand
por: Kurup, Sudheer S., et al.
Publicado: (2022)

Impact of an aryl bulky group on a one-pot reaction of aldehyde with malononitrile and N-substituted 2-cyanoacetamide
por: Vala, Ruturajsinh M., et al.
Publicado: (2019)

Regioselective Enzymatic Carboxylation of Phenols and Hydroxystyrene Derivatives
por: Wuensch, Christiane, et al.
Publicado: (2012)

Regioselective Enzymatic Carboxylation of Bioactive (Poly)phenols
por: Plasch, Katharina, et al.
Publicado: (2017)

When a Feller Is Off’n His Feed
Publicado: (1899)

Dendrimers Functionalized with Palladium Complexes of N-, N,N-, and N,N,N-Ligands
por: Vanbellingen, Quentin, et al.
Publicado: (2021)

Unusually Efficient Pyridine Photodissociation from Ru(II) Complexes with Sterically Bulky Bidentate Ancillary Ligands
por: Knoll, Jessica D., et al.
Publicado: (2014)

The Steric Effect in Preparations of Vanadium(II)/(III) Dinitrogen Complexes of Triamidoamine Ligands Bearing Bulky Substituents
por: Kokubo, Yoshiaki, et al.
Publicado: (2022)

Oxygenase-Catalyzed Desymmetrization of N,N-Dialkyl-piperidine-4-carboxylic Acids**
por: Rydzik, Anna M, et al.
Publicado: (2014)

Supramolecular architectures and structural diversity in a series of lead (II) Chelates involving 5-Chloro/Bromo thiophene-2-carboxylate and N,N’-donor ligands
por: Jennifer, Samson Jegan, et al.
Publicado: (2013)

An N.A.M.H. Conference Debates the E.S.N. School-Leaver and His Problems
Publicado: (1962)

Cannot write session to /tmp/vufind_sessions/sess_unp0sr3oh2tq8kg04604ahek9d