Iron Catalyzed Double Bond Isomerization: Evidence for an Fe(I)/Fe(III) Catalytic Cycle

Iron‐catalyzed isomerization of alkenes is reported using an iron(II) β‐diketiminate pre‐catalyst. The reaction proceeds with a catalytic amount of a hydride source, such as pinacol borane (HBpin) or ammonia borane (H(3)N⋅BH(3)). Reactivity with both allyl arenes and aliphatic alkenes has been studi...

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Detalles Bibliográficos
Autores principales: Woof, Callum R., Durand, Derek J., Fey, Natalie, Richards, Emma, Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048803/
https://www.ncbi.nlm.nih.gov/pubmed/33492679
http://dx.doi.org/10.1002/chem.202004980

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048803/
https://www.ncbi.nlm.nih.gov/pubmed/33492679
http://dx.doi.org/10.1002/chem.202004980

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