Cargando…
Iron Catalyzed Double Bond Isomerization: Evidence for an Fe(I)/Fe(III) Catalytic Cycle
Iron‐catalyzed isomerization of alkenes is reported using an iron(II) β‐diketiminate pre‐catalyst. The reaction proceeds with a catalytic amount of a hydride source, such as pinacol borane (HBpin) or ammonia borane (H(3)N⋅BH(3)). Reactivity with both allyl arenes and aliphatic alkenes has been studi...
Autores principales: | Woof, Callum R., Durand, Derek J., Fey, Natalie, Richards, Emma, Webster, Ruth L. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048803/ https://www.ncbi.nlm.nih.gov/pubmed/33492679 http://dx.doi.org/10.1002/chem.202004980 |
Ejemplares similares
-
Polymerization of Allenes by Using an Iron(II) β‐Diketiminate Pre‐Catalyst to Generate High M
(n) Polymers
por: Woof, Callum R., et al.
Publicado: (2021) -
Rational Design of a Confacial Pentaoctahedron: Anisotropic Exchange in a Linear Zn(II)Fe(III)Fe(III)Fe(III)Zn(II) Complex
por: Walleck, Stephan, et al.
Publicado: (2021) -
Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases
por: Winkler, Martin, et al.
Publicado: (2017) -
[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential
por: Schippers, Esther C. F., et al.
Publicado: (2019) -
As(iii) removal through catalytic oxidation and Fe(iii) precipitation
por: Oshima, Kazumasa, et al.
Publicado: (2022)