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Carbon Origami via an Alumina‐Assisted Cyclodehydrofluorination Strategy

The synthesis of pristine non‐planar nanographenes (NGs) via a cyclodehydrofluorination strategy is reported and the creation of highly strained systems via alumina‐assisted C−F bond activation is shown. Steric hindrance could execute an alternative coupling program leading to rare octagon formation...

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Detalles Bibliográficos
Autores principales: Steiner, Ann‐Kristin, Sharapa, Dmitry I., Troyanov, Sergey I., Nuss, Jürgen, Amsharov, Konstantin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048823/
https://www.ncbi.nlm.nih.gov/pubmed/32871018
http://dx.doi.org/10.1002/chem.202003448