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Synthesis and Ambiphilic Reactivity of Metalated Diorgano‐Phosphonite Boranes

Unprecedented metalated phosphonite boranes were prepared from PH‐substituted precursors and silyl amides. Although potassium derivatives were thermally stable and could even be isolated and structurally characterised, lithiated analogues proved to be unstable towards self‐condensation under cleavag...

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Detalles Bibliográficos
Autores principales: Hettich, Thomas D., Rudolf, Richard, Feil, Christoph M., Birchall, Nicholas, Nieger, Martin, Gudat, Dietrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048877/
https://www.ncbi.nlm.nih.gov/pubmed/33497004
http://dx.doi.org/10.1002/chem.202005437