A Titanium‐Catalyzed Reductive α‐Desulfonylation

A titanium(III)‐catalyzed desulfonylation gives access to functionalized alkyl nitrile building blocks from α‐sulfonyl nitriles, circumventing traditional base‐mediated α‐alkylation conditions and strong single electron donors. The reaction tolerates numerous functional groups including free alcohol...

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Detalles Bibliográficos
Autores principales: Kern, Christoph, Selau, Jan, Streuff, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048938/
https://www.ncbi.nlm.nih.gov/pubmed/33539578
http://dx.doi.org/10.1002/chem.202005400

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048938/
https://www.ncbi.nlm.nih.gov/pubmed/33539578
http://dx.doi.org/10.1002/chem.202005400

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