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Isoselective Polymerization of rac‐Lactide by Aluminum Complexes of N‐Heterocyclic Carbene‐Phosphinidene Adducts
The N‐heterocyclic carbene‐phosphinidene adducts (NHC)PH were reacted with AlMe(3) in toluene to afford the monoaluminum complexes [{(IDipp)PH}AlMe(3)] and [{(IMes)PH}AlMe(3)] (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene, IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazolin‐2‐ylidene). In cont...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048956/ https://www.ncbi.nlm.nih.gov/pubmed/33555047 http://dx.doi.org/10.1002/chem.202100482 |