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Isoselective Polymerization of rac‐Lactide by Aluminum Complexes of N‐Heterocyclic Carbene‐Phosphinidene Adducts

The N‐heterocyclic carbene‐phosphinidene adducts (NHC)PH were reacted with AlMe(3) in toluene to afford the monoaluminum complexes [{(IDipp)PH}AlMe(3)] and [{(IMes)PH}AlMe(3)] (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene, IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazolin‐2‐ylidene). In cont...

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Detalles Bibliográficos
Autores principales: Bhattacharjee, Jayeeta, Peters, Marius, Bockfeld, Dirk, Tamm, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048956/
https://www.ncbi.nlm.nih.gov/pubmed/33555047
http://dx.doi.org/10.1002/chem.202100482