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Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes

[Image: see text] We have prepared and characterized a series of unprecedented group 6–group 11, N(2)-bridged, heterobimetallic [ML(4)(η(1)-N(2))(μ-η(1):η(1)-N(2))Au(NHC)](+) complexes (M = Mo, W, L(2) = diphosphine) by treatment of trans-[ML(4)(N(2))(2)] with a cationic gold(I) complex [Au(NHC)](+)...

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Detalles Bibliográficos
Autores principales: Specklin, David, Coffinet, Anaïs, Vendier, Laure, del Rosal, Iker, Dinoi, Chiara, Simonneau, Antoine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8058778/
https://www.ncbi.nlm.nih.gov/pubmed/33724789
http://dx.doi.org/10.1021/acs.inorgchem.0c03271