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Stretchable chiral pockets for palladium-catalyzed highly chemo- and enantioselective allenylation

Pyrazolones are a vital class of heterocycles possessing various biological properties and much attention is paid to the diversified synthesis of enantiopure pyrazolone derivatives. We describe here the development of diphenylphosphinoalkanoic acid based chiral bisphosphine ligands, which are succes...

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Detalles Bibliográficos
Autores principales: Zhang, Yuchen, Zhang, Xue, Ma, Shengming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8065118/
https://www.ncbi.nlm.nih.gov/pubmed/33893276
http://dx.doi.org/10.1038/s41467-021-22498-1