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Kinetics of enzyme-catalysed desymmetrisation of prochiral substrates: product enantiomeric excess is not always constant
The kinetics of enzymatic desymmetrisation were analysed for the most common kinetic mechanisms: ternary complex ordered (prochiral ketone reduction); ping-pong second (ketone amination, diol esterification, desymmetrisation in the second half reaction); ping-pong first (diol ester hydrolysis) and p...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8077619/ https://www.ncbi.nlm.nih.gov/pubmed/33968260 http://dx.doi.org/10.3762/bjoc.17.73 |